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Naghipour, Ali, Sabounchei, Sayed Javad, Sayadi, Mohsen, Panahimehr, Mohammad, Notash, Behrouz. (1394). [benzylamine-K2-C,N]1,2-bis (diphenylphosphino)- propane -k2-P,P] palladium}perchlorate, mono-nuclear complex of ortho-palladated derived from benzylamine. , (), -. doi: 10.22099/ijsts.2016.3522
Ali Naghipour; Sayed Javad Sabounchei; Mohsen Sayadi; Mohammad Panahimehr; Behrouz Notash. "[benzylamine-K2-C,N]1,2-bis (diphenylphosphino)- propane -k2-P,P] palladium}perchlorate, mono-nuclear complex of ortho-palladated derived from benzylamine". , , , 1394, -. doi: 10.22099/ijsts.2016.3522
Naghipour, Ali, Sabounchei, Sayed Javad, Sayadi, Mohsen, Panahimehr, Mohammad, Notash, Behrouz. (1394). '[benzylamine-K2-C,N]1,2-bis (diphenylphosphino)- propane -k2-P,P] palladium}perchlorate, mono-nuclear complex of ortho-palladated derived from benzylamine', , (), pp. -. doi: 10.22099/ijsts.2016.3522
Naghipour, Ali, Sabounchei, Sayed Javad, Sayadi, Mohsen, Panahimehr, Mohammad, Notash, Behrouz. [benzylamine-K2-C,N]1,2-bis (diphenylphosphino)- propane -k2-P,P] palladium}perchlorate, mono-nuclear complex of ortho-palladated derived from benzylamine. , 1394; (): -. doi: 10.22099/ijsts.2016.3522

[benzylamine-K2-C,N]1,2-bis (diphenylphosphino)- propane -k2-P,P] palladium}perchlorate, mono-nuclear complex of ortho-palladated derived from benzylamine

Iranian Journal of Science
مقالات آماده انتشار، پذیرفته شده، انتشار آنلاین از تاریخ 16 دی 1394
نوع مقاله: Regular Paper
شناسه دیجیتال (DOI): 10.22099/ijsts.2016.3522
نویسندگان
Ali Naghipour* 1؛ Sayed Javad Sabounchei2؛ Mohsen Sayadi3؛ Mohammad Panahimehr4؛ Behrouz Notash5
1Department of Chemistry, Faculty of Science, Ilam University, Ilam 69315, Iran.
2Faculty of Chemistry, Bu-Ali Sinai University, Hamedan 65174, Iran
3Department of Chemistry, Faculty of Science, University of Ilam, Ilam, Iran.
4Young Research Club, Gachsaran branch, Islamic Azad University, Gachsaran, Iran.
5Department of Chemistry, Shahid Beheshti University, G.C., Evin, Tehran, 1983963113,Iran
چکیده
This work reports the preparation of the mononuclear derivative [Pd(C6H4CH2NH2) L](ClO4) (L= dppp). The centrosymmetric mononuclear palladium complexe, was obtained by the reaction of palladium(II) acetate with benzylamine in toluene produced the acetate cyclopalladated dimer of benzylamine. Metathesis reaction of these acetate-bridged cyclopalladated complex with NaCl inwater and acetone gave N,C-orthopalladated [Pd(C6H4CH2NH2)(µ-Cl)]2 complex, which reacts with, NaClO4/dppp, to give the mononuclear derivative. The orthopalladation complexe were characterized by various spectroscopic techniques such as elemental analysis, IR, 1H, 31P, and 13C NMR. The structures of N,C-metalated complexe 3 and were determined by X-ray diffraction study.
کلیدواژه‌ها
Palladium(II) complexes؛ C-H bond activation؛ Ortho-palladation؛ N,C-Chelating؛ Benzylamine؛ Crystal structure
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