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Hexamethylenetetramine as an efficient and reusable organocatalyst in Henry reaction under mild and aqueous solution | ||
| Iranian Journal of Science | ||
| مقالات آماده انتشار، پذیرفته شده، انتشار آنلاین از تاریخ 23 شهریور 1394 | ||
| نوع مقاله: Regular Paper | ||
| شناسه دیجیتال (DOI): 10.22099/ijsts.2015.3182 | ||
| نویسندگان | ||
| Alireza Sardarian* ؛ Safoura Fathi | ||
| Chemistry Department, College of Sciences, Shiraz University | ||
| چکیده | ||
| Henry reaction is a base catalyzed reaction which can produce β-nitroalcohol or nitroethylene derivatives from the condensation of aryl aldehydes and nitromethane under different conditions. In the present article, we introduce hexamethylenetetramine as a basic organocatalyst for Henry reaction, which can produce β-nitroalcohol derivatives from the condensation of aryl aldehydes and nitromethane under different conditions. By application of this organic base, β-nitroalcohol ompounds were produced as the only product in good to excellent yields. Also reusability of hexamethylenetetramine in this reaction makes our method green. | ||
| کلیدواژهها | ||
| Henry reaction؛ β-nitroalcohol؛ organic base؛ hexamethylenetetramine | ||
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