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STRUCTURAL AND IONIC BOND STRENGTH INVESTIGATION USING PAULING ESB RULES OF NONSTOCHIOMETRIC SPINEL COMPOUNDS LixMn2O4 AND STOICHIOMETRIC Li1+yMn2-yO4, AS CATHODE MATERIALS FOR RECHARGEABLE LITHIUM-ION BATTERIES | ||
| Iranian Journal of Science | ||
| مقاله 14، دوره 29، شماره 1، اردیبهشت 2005، صفحه 135-141 اصل مقاله (367.73 K) | ||
| نوع مقاله: Regular Paper | ||
| شناسه دیجیتال (DOI): 10.22099/ijsts.2005.2791 | ||
| نویسندگان | ||
| M. ALAVI* 1؛ E. M. KELDER2؛ J. SCHOONMAN2 | ||
| 11Department of Chemistry, University of Esfahan, I. R. of Iran | ||
| 2Laboratory for Applied Inorganic Chemistry, Delft University of Technology, The Netherlands | ||
| چکیده | ||
| In this paper we present our studies using Pauling electrostatic bond strength (ESB) rules for structural behaviour, cation vacancies, relation between x, y, and the valence of cations and coordination in spinel compounds LixMn2O4, 0<x<1 and Li1+yMn2-yO4, 0<y<1/3, which are of interest as the positive electrodes for rechargeable lithium-ion batteries. | ||
| کلیدواژهها | ||
| Lithium-ion battery؛ pauling’s E. S. B. rules؛ spinel | ||
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