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JARRAHPOUR, A., ALVAND, P.. (1385). SYNTHESIS OF SOME NEW SUGAR BASED 3, 3-DISUBSTITUTED MONOCYCLIC Β-LACTAMS BY ASYMMETRIC [2+2] CYCLOADDITION REACTIONS. , 31(1), 17-22. doi: 10.22099/ijsts.2007.2312
A. JARRAHPOUR; P. ALVAND. "SYNTHESIS OF SOME NEW SUGAR BASED 3, 3-DISUBSTITUTED MONOCYCLIC Β-LACTAMS BY ASYMMETRIC [2+2] CYCLOADDITION REACTIONS". , 31, 1, 1385, 17-22. doi: 10.22099/ijsts.2007.2312
JARRAHPOUR, A., ALVAND, P.. (1385). 'SYNTHESIS OF SOME NEW SUGAR BASED 3, 3-DISUBSTITUTED MONOCYCLIC Β-LACTAMS BY ASYMMETRIC [2+2] CYCLOADDITION REACTIONS', , 31(1), pp. 17-22. doi: 10.22099/ijsts.2007.2312
JARRAHPOUR, A., ALVAND, P.. SYNTHESIS OF SOME NEW SUGAR BASED 3, 3-DISUBSTITUTED MONOCYCLIC Β-LACTAMS BY ASYMMETRIC [2+2] CYCLOADDITION REACTIONS. , 1385; 31(1): 17-22. doi: 10.22099/ijsts.2007.2312

SYNTHESIS OF SOME NEW SUGAR BASED 3, 3-DISUBSTITUTED MONOCYCLIC Β-LACTAMS BY ASYMMETRIC [2+2] CYCLOADDITION REACTIONS

Iranian Journal of Science
مقاله 3، دوره 31، شماره 1، اردیبهشت 2007، صفحه 17-22    اصل مقاله (225.13 K)
نوع مقاله: Regular Paper
شناسه دیجیتال (DOI): 10.22099/ijsts.2007.2312
نویسندگان
A. JARRAHPOUR* ؛ P. ALVAND
Chemistry Department, College of Sciences, Shiraz University, Shiraz 71454, I. R of Iran
چکیده
Synthesis of some new monocyclic β-lactams containing a quaternary carbon center via a [2+2]
cycloaddition reaction is described. The reaction of achiral diphenyl ketene with chiral aldimines derived
from chiral 2, 3, 4, 6-tetra-O-acetyl-β-D-galactopyranosylamine, 2, 3, 4, 6-tetra-O-acetyl-β-Dglucopyranosylamine and different benzaldehydes resulted in the formation of β-lactams as single
diastereomers.
کلیدواژه‌ها
-2-azetidinone؛ asymmetric synthesis؛ chiral Schiff bases؛ sugar؛ [2+2] cycloaddition
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