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Lin, Ji-Zi. (1392). Theoretical studies of the optical spectra and EPR parameters for VO2+ ions in Zn(antipyrine)2(NO3)2. , 37(4), 453-456. doi: 10.22099/ijsts.2013.1781
Ji-Zi Lin. "Theoretical studies of the optical spectra and EPR parameters for VO2+ ions in Zn(antipyrine)2(NO3)2". , 37, 4, 1392, 453-456. doi: 10.22099/ijsts.2013.1781
Lin, Ji-Zi. (1392). 'Theoretical studies of the optical spectra and EPR parameters for VO2+ ions in Zn(antipyrine)2(NO3)2', , 37(4), pp. 453-456. doi: 10.22099/ijsts.2013.1781
Lin, Ji-Zi. Theoretical studies of the optical spectra and EPR parameters for VO2+ ions in Zn(antipyrine)2(NO3)2. , 1392; 37(4): 453-456. doi: 10.22099/ijsts.2013.1781

Theoretical studies of the optical spectra and EPR parameters for VO2+ ions in Zn(antipyrine)2(NO3)2

Iranian Journal of Science
مقاله 4، دوره 37، شماره 4، اسفند 2013، صفحه 453-456    اصل مقاله (196.04 K)
نوع مقاله: Regular Paper
شناسه دیجیتال (DOI): 10.22099/ijsts.2013.1781
نویسنده
Ji-Zi Lin*
Department of Physics, Jiangsu University of Science and Technology Changxing Road, Zhangjiagang, 215600, P. R. China
چکیده
The optical spectrum band positions and EPR parameters (g factors g//, g^ and hyperfine structure constants A// and A^) for VO2+ ions in Zn(antipyrine)2(NO3)2 are theoretically studied from the complete diagonalization (of energy matrix) method (CDM) and the perturbation theory method (PTM). In the two methods, the contributions from the spin–orbit (SO) coupling of central 3dn ion and ligand are taken into account. The theoretical results from both methods are not only consistent with the experimental values, but also close to each other. The results are discussed.
کلیدواژه‌ها
Electron paramagnetic resonance (EPR)؛ Crystal-fields and Spin Hamiltonians؛ VO2+；Zn(antipyrine)2 (NO3)2
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